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Lithium Superionic Conductivity

Lithium Superionic Conductivity
Using a complex hydride with superionic conductivity in a solid electrolyte may move the needle forward in the development of solid-state lithium batteries.

As regular Design News readers will know, the hottest topic in battery technology these days is solid-state lithium batteries. It seems every week a new breakthrough or innovation is announced that will make this promising new technology possible. At DN, we feel obligated to report on much of this research—not because we want to add to the hype, but because solid-state lithium batteries hold so much promise to dramatically improve the lithium ion batteries that are commercially available.

A high-energy-density, solid-state lithium metal battery might be improved by employing complex hydrides in the solid electrolyte. (Image source: Sangryun Kim and Shin-ichi Orimo)

High Ionic Conductivity

As a case in point, researchers at Tohoku University in Japan have announced, via a news release, a new solid electrolyte that exhibits high ionic conductivity and high stability against the lithium metal that is used as the anode in solid-state lithium batteries. Lithium metal can provide up to three times the charge capacity when compared to the graphite anode used in lithium ion batteries. But when a metallic lithium anode is used with a typical liquid electrolyte, spikey dendritic crystals of lithium can form on the metal surface. These dendrites can eventually short out the battery cell, and can potentially cause a fire.

A solid electrolyte, when used with a metallic lithium anode, has been shown to limit the growth of the dendritic crystals. But, the use of solid and semi-solid electrolytes has been limited by the high lithium ion transfer resistance, caused mainly by the instability of the solid electrolyte against lithium metal. This can cause unwanted side-reactions at the interface between the lithium metal and the electrolyte.

Hydrogen Clusters

That’s where the new research from Tohoku University comes in. In the news release, the researchers say, “…the new material, achieved by designing structures of hydrogen clusters (complex anions), shows markedly high stability against lithium metal, which would make it the ultimate anode material for all-solid-state batteries.”

Sangryun Kim of Shin-ichi Orimo's research group at Tohoku University described the material. "Complex hydrides have received a lot of attention in addressing the problems associated with the lithium metal anode because of their outstanding chemical and electrochemical stability against the lithium metal anode," said Kim. "But because of their low ionic conductivity, using complex hydrides with the lithium metal anode have never been attempted in practical batteries. So we were very motivated to see if developing complex hydride that exhibit lithium superionic conductivity at room temperature can enable the use of lithium metal anode. And it worked."

Although the research is in the early stages, it does represent yet another possibility for the eventual adoption of lithium metal anodes and solid state electrolytes. "We expect that this development will not only inspire future efforts to find lithium superionic conductors based on complex hydrides, but also open up a new trend in the field of solid electrolyte materials that may lead to the development of high-energy-density electrochemical devices," said Kim.

Senior Editor Kevin Clemens has been writing about energy, automotive, and transportation topics for more than 30 years. He has masters degrees in Materials Engineering and Environmental Education and a doctorate degree in Mechanical Engineering, specializing in aerodynamics. He has set several world land speed records on electric motorcycles that he built in his workshop.


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