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Materials & Assembly
The Plastics Environmental Council (PEC) is sponsoring research to produce the first standard specification for landfill biodegradation of petroleum- and natural gas-derived plastics treated with additives to speed up anaerobic biodegradation. Such a standard would be a huge help in coping with the estimated 29 million tons of post-consumer nonrecycled plastics that end up in landfills.
Plastics are generally not biodegradable unless they've been specifically engineered to do so, as materials used in food service items are in many areas of California. Petroleum-derived plastics don't usually biodegrade unless they've had certain chemical additives introduced to them during the manufacturing process. The additives don't affect the plastics' performance, and products that contain the additives can be processed with existing recycling methods.
An additive made by ENSO Plastics , a PEC member, includes organic compounds that bond hydrostatically to the material's molecules. When the material is placed in an environment like a landfill, the additive attracts anaerobic microbes that colonize the plastic, digest the additive, and further digest the plastic by depolymerizing it. The final products are either methane or carbon dioxide and humus.
The PEC-sponsored large-scale research and development program will be conducted by the Georgia Institute of Technology and North Carolina State University and aims to produce a specification and a certification seal. The specification will reliably project landfill biodegradation rates for a given PEC-certified product in a given range of landfills over a given range of moisture conditions. The PEC expects the development of the specification to build confidence among regulators, consumers, and businesses in the effectiveness of plastics additives. It estimates the certification seal will be available in 18 months.
The study will be the first of its kind to verify biodegradation rates of plastic waste treated with additives under both laboratory and field conditions, Robert McKnight, the PEC's chairman, said in a press release .
Professor Morton Barlaz of North Carolina State and his team will examine waste degradation rates under both field and laboratory conditions. To produce the specification, they will study petroleum- and natural gas-derived plastics that have been treated with additives from PEC member companies.
The additives are organic substances that encourage anaerobic landfill bacteria and fungi to break down the materials and convert them to biogas methane, carbon dioxide, and biogenic carbon. "Research done so far using standard test methods suggests that the treated plastics could biodegrade completely within five to ten years, depending on landfill conditions," Lisa Detter Hoskin, a principal research scientist at the Georgia Tech Research Institute, who co-chairs the PEC’s technical advisory committee, said in a press release . A network of accredited laboratories will test products made with the biodegradable additives to ensure they degrade within a specified period.
PEC member companies include Biofilms, Bio-Tec Environmental, C-Line Products, ECM, Ecolab, Ecologic, FP International, Pure Plastics, and Wincup.
Re: Biodegradable Plastics Standard to Bust Landfill Waste
Ann R. Thryft
1/12/2012 12:17:23 PM
sjmonte, thanks for the (extremely long!) post, but it's completely unreadable because of the lack of spacing. It looks like you are copying and pasting directly from your website instead of from some kind of text document. Perhaps, instead of copying and pasting, you can provide links for us to check out.
Re: Biodegradable Plastics Standard to Bust Landfill Waste
sjmonte@4kenrich.com
11/23/2011 2:43:15 PM
todavidpalmer: ihavere-postedmypreviousmessagewithspacingbelow. asyoucannowsee,item2addressestheissueofrecyclability. thetitanateadditivewillnotonlynot interferewithuserecycling,itwillcopolymerizethedissimilarpolymersinthemeltactingasatitanocene-like(metallocene)catalystimprovingmeltflowandmechanicalproperties. seespegpectechpapersandothers:titanatesandzirconatesforrecycled,compostableandbiobasedpolymercomposites–gpec2009 titanateandzirconatecouplingagents–akeytoenvironmentalinnovation-gpec2007 ifiledapatentin1989on"bioreversibleconventionalplastics",butitwaspreemptedbyanotheroneofmypriorcomposition-of-mattertitanatepatents.ifyouwishtodiscussingreaterdetail,icanhavemichellem.monte,vpgeneralcounselsendyouourstraightforward,mutualndaforyourreview. re-post: anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html
Re: Biodegradable Plastics Standard to Bust Landfill Waste
Dave Palmer
11/23/2011 2:15:31 PM
@Salvatore: Your comment is almost unreadable due to the lack of spaces between any of the words. If you click on "Edit/Delete," you can fix this.
However, being a curious mind, I took a look at your website. It's interesting to know that you were working on this already in the late 1980s, and that there has been an ASTM standard for anaerobic biodegradation of plastics in landfills since 1994. Apparently this is not such a new topic.
My question for you is the same as my question for all of the other additive manufacturers - what happens if plastics with your additive make their way into the recycling stream? Will they degrade the properties of recycled plastics?
Given that environmentally-conscious consumers (the same ones who are likely to pay extra for a biodegradable product) have been trained to reduce/reuse/recycle, re-training them to not recycle could be difficult.
anaerobicbiodegradationofconventionalplasticsisalreadycoveredbyastmd5526-94,whichbasicallyrequiresacontrolledlandfillhavinggreaterthan40%moisture,nooxygen,nosunlight,andanaerobicmicrobessuchasprovidedintheformofgarbageandfeces.theplasticsenvironmentalcouncil(pec)shouldkeeptheastmstandardinmindsothattheydon'treinventthewheel,butimproveonit. itispossibletocauseanaerobicbiodegradationofconventionalplasticsbyforminganetworkof1.5-nanometerhydrophilictitanatesthatattractmoistureintotheconventionalpolymertoallowtheanaerobicmicrobestobreakdownthepolymerchainsandallowthetitaniumcatalysttodepolymerizethepolymerfurthertobiomassandbiogas. thetitanatehydrophilic/depolymeizationmechanismisdesirablebecauseduringtheintendedlifetimeanduseoftheconventionalplasticcontainingtheadditive: 1.theplasticsproperties,morphology,viscosityreductionoffillers,moldability,andflameretardancyareenhancedasisestablishedintheartwithhydrophobictitanates. 2,neoalkoxy,monoalkoxy,chelate,andcoordinatetypetitanatesareprovenrepolymerizationandcopolymerizationcatalystsinairandoxygenenvironmentsandassistinrecyclingandprocessing. 3.plasticsarenotusedunderastmd5526-94conditions-theyaregarbage. wehaveestablisheddatafortheanaerobicbiodegradationofconventionalpvcfromathirdpartylaboratoryforwhichwepaidforthestudy. wealsostudiedothermaterialssuchaspp,eva,lldpe,epr,etc.andcameuppartiallynegative,andneedtodomoreworkonmodificationoftheastmd5526-94standardtoreplicatethebiodegradationeffectswehavebeenworkingoninourlaboratorysince1989. ofcourse,pvcformulationscanbecomplexwithstabilizerssuchasznandotheranti-bacterialadditivesthatinterferewiththeanaerobicbiodegradationmechanism. myultimategoalisreplicatetheoldcloth-diaperreplacementserviceusingdisposablediapersandconverttheppnon-wovens-6%ofthesolidsinlandfill-inanincubationfactoryintobiomassandbiogasforelectricitygenerationintothepowergrid. oncewegettheanaerobicbiodegradationmechanismfirmlyestablishedasapracticaladditiveandprocess,itwilltakeaholisticeffortbythepolymerproducer,non-wovenfabricator,diaperproducer,point-of-salemarketing,trucking-deliveryservice,municipal,stateandfederalauthoritiestomakeithappen. salmonte-kenrichpetrochemicals,inc.http://www.4kenrich.com/content/officers.html
Oxodegradable additives
TimDunn
11/21/2011 5:23:41 PM
I have never seen a study verifying that an ordinary oxodegradable product such as a shopping bag will biodegrade given its normal treatment - taken to the landfill in the trash, where it will be covered in more trash within a day or two, if not immediately. Based on the published science, I agree with the DEPRA report, which found that they will not biodegrade in landfills. This DEPRA report was the reason why COOP and Tesco, the largest grocery chains in Great Britain, stopped using oxodegradable additives in their bags. As far as methane goes, it's being tapped and used in place of ordinary natural gas. In fact, much of the methane generated in landfills is eaten by microbes in the landfills. See http://earthnurture.com/LandfillCondTD.html to learn more.
Biogas
TimDunn
11/21/2011 5:18:37 PM
Landfills are complicated places. To learn about biogas and landfills see:
http://earthnurture.com/LandfillCondTD.html
Re: A new class of additives to induce biodegradation in polymers
TimDunn
11/21/2011 5:16:58 PM
Enso is not a manufactuer of additives, it is a dealer specializing in an additive for biodegrading PET. They represent Bio-Tec, which makes the additive. My additives are in the same general class, but they are a more thorough, more recent technology.
Re: A new class of additives to induce biodegradation in polymers
TimDunn
11/21/2011 5:13:50 PM
Hydrobiodegradable plastics are a plastic type, and the best known example is PLA. Oxodegradable additives are additives mixed with polyolefinic plastics, to act as a catalyst to chemically degrade them. The reason some moisture is required is to sustain the lives of the microorganisms. It has been said that the most germ-fee place in the average home is the toilet seat, because it is so dry. My additives work with all of the typical commodity plastics - PP, PE, HDPE, LDPE, LLDPE, PS, EPS, PET. I have designed one additive that will render PLA biodegradable in landfills. PLAs most prominent manufacturer says it is not biodegradable in landfills. See http://earthnurture.com for full details.
Re: A new class of additives to induce biodegradation in polymers
Ann R. Thryft
11/21/2011 12:34:59 PM
Tim, this sounds very interesting. I believe that hydrobiodegradable and oxobiodegradable are terms describing the two basic classes of plastics, not of additives. Does your additive work for one of these classes? The additives described in the research mentioned in this article work anaerobically in moist and/or wet environments, e.g., landfills and bodies of water. That implies that your additive works with hydrobiodegradable plastics. Is that correct?
Re: A new class of additives to induce biodegradation in polymers
Dave Palmer
11/21/2011 11:38:43 AM
@TimDunn: How do the additives which your company sells differ from the ones discussed in this article, (for example, the ones made by ENSO)?
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