Researchers at Stanford University have built a prototype of an all-carbon solar cell that includes carbon nanotubes in both the photoactive layer and the electrodes. (Source: Mark Shwartz / Stanford University)
akwaman, I totally agree with you about solar. We've known for decades about how much energy there is free for our use and have done relatively little with that knowledge except invent an industry--PV solar--that makes all that sunlight a lot more difficult and expensive to use than it needs to be. I also agree about the hot water advantage: that's where I saw the heat storage potential of rocks and water used to best advantage--way back in the 70s.
Hats off to those forward thinkers at Stanford! Ann, I know it is hard to believe, but the best passive use for solar is... tanning! LOL... just kidding. You are correct that passive use of solar it a good thing that is certainly not utilized enough. Light tubes and better house design should absolutely be integrated into all modern designs (but they are not). But seriously overlooked is solar hot water, which would save this country an enormous amount of power requirements (the avg is 30% of utility bill from hot water), and it is VERY cost effective, much more so than solar PV. There have been recent advancements in PV that I believe will provide 25% or bettter efficiency in the next 10 years commercially, using cheaper technology than available today. But it must be coupled with other forms of solar power generation, like the hot salt method, that retains heat and provides power through the night without batteries. The sun provides more power than we can even use, we just have to figure out how to harness it the best and most efficient way.
Thanks, Cadman-LT and akwaman. Thinking out of the box is something Stanford is known for, so I like to follow that university's research efforts (along with Harvard and MIT). But I'm still not convinced that any form of active solar--PV or otherwise--is the best way to do solar. Sunlight can be used for passive solar, which has a history of a few thousand years of human engineering. I've seen some amazing results of combining that old know-how with modern, precise engineering.
This is a perfect example of thinking out-of-the-box, which is necessary to make the advancements in solar photovoltaics. It won't take much to make solar photovoltaics mainstream and part of every home, everywhere. Sunlight is the largest and most under-utilized source of energy we have on the planet.
Silicon may be cheap as a raw material, but not so much when it's processed to make wafers, in this case, solar wafers and cells. On the one hand, the solar industry began by leveraging the huge existing infrastructure for manufacturing silicon wafers, assuming this would be the fastest way to getting costs down. That was a reasonable assumption at the time, but the reality has proven to be a bit more complex. As the article states, silicon processing steps can be many and they're not cheap. Thin-film is not a monolithic manufacturing method. The cost of thin-film to make solar cells is highly variable, and depends on many factors, including base materials, coating methods, and the coating itself. But this particular method does away with wafers altogether, which is a major potential of thin-film, and the material's potential means better conductivity and light absorption for low cost.
The photoabsorber is a diminishing part of the cost of a solar module and efficiency is it's salient attribute. As for abundance, silica is 60% of the continental crust - it's literally everywhere, even if you restrict yourself to clean beach sand. And, it's literally dirt cheap. The cost in a photoabsorber material is in the processing of it not the raw material.
The transparent conductor in most production thin film panels is tin oxide (not ITO) where tin oxide coated glass is a commodity in the glazing industry i.e. not specific to solar modules and therefore cost optimized. The next alternatives are various zinc oxide alloys.
The back contact/mirror in production modules is generally not silver although, even when it is, it is a very thin coat. More commonly it is a nickel or aluminum alloy.
Keep in mind that the primary value proposition of thin film is low cost offsetting low efficiency. The problem for thin film is that the cost of solar grade silicon has plumeted (~10X since I started with solar), the utilization of silicon (grams per Watt) has been reduced (~3X) and efficiency has increased (~50%). Over my brief history, the cost of silicon photoabsorer in $/W terms has gone down ~45X. Another advantage of silicon is that 25+ year operating lifetimes have been demonstrated.
It's easy to forget that any technology requires an entire ecosystem to support it - that's why it takes so long for it to emerge as a commercial product if ever. The first semiconductor solar cell was demonstrated in 1888, the first silicon cel in 1954 and yet silicon solar cells are still not a mature technology.
Don't rain on their parade! They acknowledge that efficiency is being worked on, and one would expect it to be low at this point. This is something others have been chasing for decades with other solar cell materials too, which had horrible efficiency at first. (Or still does.) But say this costs half as much, but has half the energy efficiency. A net zero, disregarding real estate required. And if you can put it on the glass of a office tower which is already a net waste of energy, awesome.
I get excited at every article like this, whether it's batteries, solar, wind, wave, etc. I'm hoping for those big breakthroughs, i.e. game-changing scientific and engineering accomplishments that will go a long way to eliminating fossil fuels. That carbon was sequestered for eons, and we are freeing it without much regard for future effects.
GeorgeG, 'photoabsorbers' is a new term for me, and I found nothing on a Google search page.
Full disclosure- I have a lovely FL home which at high tide, is just a few feet above sea level!
Exactly: efficiency is king - especially now as the cost of photoabsorbers is becoming a fraction of the cost of a solar module. For an emerging technology, the first number to look at is the theoretical efficiency with the guesstimate that ultimately volume production product will achieve approximately 80% of that.
Most of the new 3D printers and 3D printing technologies in this crop are breaking some boundaries, whether it's build volume-per-dollar ratios, multimaterials printing techniques, or new materials types.
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